An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

A novel strategy has been developed to construct a highly stable core-shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π-π stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel co...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-05, Vol.55 (45), p.6377-638
Hauptverfasser: Gao, Ming-Liang, Qi, Mei-Hong, Liu, Lin, Han, Zheng-Bo
Format: Artikel
Sprache:eng
Schlagworte:
Cascade chemical reactions
Catalysis
Catalysts
Chemical synthesis
Condensates
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Zusammenfassung:A novel strategy has been developed to construct a highly stable core-shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π-π stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction. A novel strategy has been developed to construct a highly stable core-shell MOF@COF bifunctional catalyst through strong π-π stacking interaction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc02174d