Bi- and Multilayered Assembly of Amphiphilic Pd(II) and Pt(II) Complexes with N-Alkyl-4,4′-bipyridinium Ligands

Bi- and Multilayered Assembly of Amphiphilic Pd(II) and Pt(II) Complexes with N-Alkyl-4,4′-bipyridinium Ligands

Alternating transition metal-organic bi- and multilayers composed of dicationic (ethylenediamine)palladium(II) and platinum(II) complexes and N-alkyl-4,4′-bipyridinium, [(η3–C3H5)Pd{4,4′-bpy-N-(CH2)12OC6H3-3,5-(OMe)2}(OAc)]NO3 and [M{4,4′-bpy-N-(CH2)12OC6H3-3,5-(OMe)2}2(en)](NO3)4 (M = Pd, Pt, en =...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2016-09, Vol.89 (9), p.1069-1071
Hauptverfasser: Endo, Hirotaka, Suzaki, Yuji, Komura, Motonori, Osakada, Kohtaro
Format: Artikel
Sprache:eng
Schlagworte:
Aqueous solutions
Ethylenediamine
Mica
Multilayers
Palladium
Platinum
Transition metals
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Beschreibung
Zusammenfassung:Alternating transition metal-organic bi- and multilayers composed of dicationic (ethylenediamine)palladium(II) and platinum(II) complexes and N-alkyl-4,4′-bipyridinium, [(η3–C3H5)Pd{4,4′-bpy-N-(CH2)12OC6H3-3,5-(OMe)2}(OAc)]NO3 and [M{4,4′-bpy-N-(CH2)12OC6H3-3,5-(OMe)2}2(en)](NO3)4 (M = Pd, Pt, en = 1,2-ethylenediamine), were synthesized on mica surface by simple casting method from aqueous solution.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20160131