Polyfluoroalkyl Phosphates Bearing Propargyl Substituents

Polyfluoroalkyl dichlorophosphates react easily with propargyl alcohol under mild conditions (22–62°С, 3 h, pyridine-toluene) to form previously unknown bis(2-propynyl) polyfluoroalkyl phosphates with a yield of 36–41%, a triple bond in which is capable of participating in the azide-alkyne cycloaddi...

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Veröffentlicht in:Russian journal of general chemistry 2019-04, Vol.89 (4), p.708-712
Hauptverfasser: Verkhoturova, S. I., Nalibaeva, A. M., Arbuzova, S. N., Kazantseva, T. I., Zinchenko, S.V., Mikhailenko, V. L., Chernysheva, N. A., Bishimbaeva, G. K., Gusarova, N. K., Trofimov, B. A.
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Sprache:eng
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Zusammenfassung:Polyfluoroalkyl dichlorophosphates react easily with propargyl alcohol under mild conditions (22–62°С, 3 h, pyridine-toluene) to form previously unknown bis(2-propynyl) polyfluoroalkyl phosphates with a yield of 36–41%, a triple bond in which is capable of participating in the azide-alkyne cycloaddition reaction.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321904011X