New application of indium catalysts: A novel and green concept in the fine chemicals industry

New industrially important catalytic processes for application in the fine chemicals industry (e.g., synthesis of vitamins and key-intermediates) are presented. Protocols with indium catalysts provide the advantages of high selectivity and low catalyst loading for Friedel-Crafts-type alkylation, Wag...

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Veröffentlicht in:	Pure and applied chemistry 2007-11, Vol.79 (11), p.1839-1846
Hauptverfasser:	Wildermann, Angela, Foricher, Yann, Netscher, Thomas, Bonrath, Werner
Format:	Artikel
Sprache:	eng
Schlagworte:	Acylation Alkylation Catalysis Catalysts Chemical industry Fine chemicals Friedel–Crafts reaction green chemistry Indium Organic chemistry rearrangements Selectivity tocopherol Vitamins
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Beschreibung
Zusammenfassung:	New industrially important catalytic processes for application in the fine chemicals industry (e.g., synthesis of vitamins and key-intermediates) are presented. Protocols with indium catalysts provide the advantages of high selectivity and low catalyst loading for Friedel-Crafts-type alkylation, Wagner-Meerwein rearrangement, and acylation reactions. The transformations discussed could be carried out in a continuous manner.
ISSN:	0033-4545 1365-3075
DOI:	10.1351/pac200779111839