Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions
The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination)...
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| Veröffentlicht in: | Pure and applied chemistry 2010-05, Vol.82 (7), p.1503-1515 |
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| container_issue | 7 |
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| container_title | Pure and applied chemistry |
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| creator | Eisenberger, Patrick Schafer, Laurel L. |
| description | The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination) and C–C (hydroaminoalkylation) bond-forming reactions to access substituted amines. |
| doi_str_mv | 10.1351/PAC-CON-09-11-27 |
| format | Article |
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Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination) and C–C (hydroaminoalkylation) bond-forming reactions to access substituted amines.</description><subject>amidate</subject><subject>Amines</subject><subject>asymmetric catalysis</subject><subject>Catalysis</subject><subject>catalytic amine synthesis</subject><subject>Chemical synthesis</subject><subject>Coordination compounds</subject><subject>C–C bond formation</subject><subject>C–H activation</subject><subject>C–N bond formation</subject><subject>hydroamination</subject><subject>hydroaminoalkylation</subject><subject>Oxidation</subject><subject>tantalum</subject><subject>Transition metals</subject><subject>zirconium</subject><issn>0033-4545</issn><issn>1365-3075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp1kctqGzEUhkVJoY7bfZeCrJXoOpdughnSJGDsLtq10Egae8yM5Ehy0tkF-gh9wzxJ5DjQVVfnLP7vO_AfAL4SfEmYIFc_Fg1q1iuEa0QIouUHMCOsEIjhUpyBGcaMIS64-ATOY9xhjHnN6Qz8aVRSw5R6DePk0tbGPkLfQTX2zkaonIErpL1Lqne928CtTTZ4PenBxm9wMfZGJQu1H_eD_Z2BzgcY7WB16h8tbF6e_67eJMetga13BuXIeFQFq3LKu_gZfOzUEO2X9zkHv77f_Gzu0HJ9e98slkhzJhIyteKsZqyjlFSkbo1pGTWUc6KJxqKsqpIoRTujClwpXBRtQdqSca6NEnVB2RxcnLz74B8ONia584fg8klJKcOUvafwKaWDjzHYTu5DP6owSYLlsWqZq5a5aolrSYikZUauT8iTGnI9xm7CYcrLP___0IqWROTXvAJAFojr</recordid><startdate>20100531</startdate><enddate>20100531</enddate><creator>Eisenberger, Patrick</creator><creator>Schafer, Laurel L.</creator><general>De Gruyter</general><general>Walter de Gruyter GmbH</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope></search><sort><creationdate>20100531</creationdate><title>Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions</title><author>Eisenberger, Patrick ; Schafer, Laurel L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-d9a43933f221819bddb32d2441c1c0578871aa2fda608a066b61b7344cda59623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>amidate</topic><topic>Amines</topic><topic>asymmetric catalysis</topic><topic>Catalysis</topic><topic>catalytic amine synthesis</topic><topic>Chemical synthesis</topic><topic>Coordination compounds</topic><topic>C–C bond formation</topic><topic>C–H activation</topic><topic>C–N bond formation</topic><topic>hydroamination</topic><topic>hydroaminoalkylation</topic><topic>Oxidation</topic><topic>tantalum</topic><topic>Transition metals</topic><topic>zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eisenberger, Patrick</creatorcontrib><creatorcontrib>Schafer, Laurel L.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Pure and applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eisenberger, Patrick</au><au>Schafer, Laurel L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions</atitle><jtitle>Pure and applied chemistry</jtitle><date>2010-05-31</date><risdate>2010</risdate><volume>82</volume><issue>7</issue><spage>1503</spage><epage>1515</epage><pages>1503-1515</pages><issn>0033-4545</issn><eissn>1365-3075</eissn><abstract>The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. 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| fulltext | fulltext |
| identifier | ISSN: 0033-4545 |
| ispartof | Pure and applied chemistry, 2010-05, Vol.82 (7), p.1503-1515 |
| issn | 0033-4545 1365-3075 |
| language | eng |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
| subjects | amidate Amines asymmetric catalysis Catalysis catalytic amine synthesis Chemical synthesis Coordination compounds C–C bond formation C–H activation C–N bond formation hydroamination hydroaminoalkylation Oxidation tantalum Transition metals zirconium |
| title | Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions |
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