Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination)...

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Veröffentlicht in:Pure and applied chemistry 2010-05, Vol.82 (7), p.1503-1515
Hauptverfasser: Eisenberger, Patrick, Schafer, Laurel L.
Format: Artikel
Sprache:eng
Schlagworte:
amidate
Amines
asymmetric catalysis
Catalysis
catalytic amine synthesis
Chemical synthesis
Coordination compounds
C–C bond formation
C–H activation
C–N bond formation
hydroamination
hydroaminoalkylation
Oxidation
tantalum
Transition metals
zirconium
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Beschreibung
Zusammenfassung:The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination) and C–C (hydroaminoalkylation) bond-forming reactions to access substituted amines.
ISSN:0033-4545
1365-3075
DOI:10.1351/PAC-CON-09-11-27