Radical Metalloids with N-Heterocyclic Carbene and Phenanthroline Ligands: Synthesis, Properties, and Cross-Coupling Reaction of [(Nitronyl Nitroxide)-2-ido]metal Complexes with Aryl Halides

New radical metalloids, NN-AuSIMes and NN-Cu(bdmpphen), were prepared and their properties were investigated. They were applied to Pd(0)-mediated cross-coupling reactions with aryl halides (ArX) to produce 2-aryl (nitronyl nitroxide)s in moderate to high yields.

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2018-07, Vol.91 (7), p.1150-1157
Hauptverfasser:	Yamada, Kiyomi, Zhang, Xun, Tanimoto, Ryu, Suzuki, Shuichi, Kozaki, Masatoshi, Tanaka, Rika, Okada, Keiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Chemical reactions Chemical synthesis Coordination compounds Copper Cross coupling Halides Metalloids Palladium
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container_title	Bulletin of the Chemical Society of Japan
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creator	Yamada, Kiyomi Zhang, Xun Tanimoto, Ryu Suzuki, Shuichi Kozaki, Masatoshi Tanaka, Rika Okada, Keiji
description	New radical metalloids, NN-AuSIMes and NN-Cu(bdmpphen), were prepared and their properties were investigated. They were applied to Pd(0)-mediated cross-coupling reactions with aryl halides (ArX) to produce 2-aryl (nitronyl nitroxide)s in moderate to high yields.
doi_str_mv	10.1246/bcsj.20180033
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Aromatic compounds Chemical reactions Chemical synthesis Coordination compounds Copper Cross coupling Halides Metalloids Palladium
title	Radical Metalloids with N-Heterocyclic Carbene and Phenanthroline Ligands: Synthesis, Properties, and Cross-Coupling Reaction of [(Nitronyl Nitroxide)-2-ido]metal Complexes with Aryl Halides
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