Radical Metalloids with N-Heterocyclic Carbene and Phenanthroline Ligands: Synthesis, Properties, and Cross-Coupling Reaction of [(Nitronyl Nitroxide)-2-ido]metal Complexes with Aryl Halides

Radical Metalloids with N-Heterocyclic Carbene and Phenanthroline Ligands: Synthesis, Properties, and Cross-Coupling Reaction of [(Nitronyl Nitroxide)-2-ido]metal Complexes with Aryl Halides

New radical metalloids, NN-AuSIMes and NN-Cu(bdmpphen), were prepared and their properties were investigated. They were applied to Pd(0)-mediated cross-coupling reactions with aryl halides (ArX) to produce 2-aryl (nitronyl nitroxide)s in moderate to high yields.

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2018-07, Vol.91 (7), p.1150-1157
Hauptverfasser: Yamada, Kiyomi, Zhang, Xun, Tanimoto, Ryu, Suzuki, Shuichi, Kozaki, Masatoshi, Tanaka, Rika, Okada, Keiji
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Chemical reactions
Chemical synthesis
Coordination compounds
Copper
Cross coupling
Halides
Metalloids
Palladium
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Beschreibung
Zusammenfassung:New radical metalloids, NN-AuSIMes and NN-Cu(bdmpphen), were prepared and their properties were investigated. They were applied to Pd(0)-mediated cross-coupling reactions with aryl halides (ArX) to produce 2-aryl (nitronyl nitroxide)s in moderate to high yields.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20180033