Kinetics of Alloy Emission Spectra with Double-Pulse Laser Ablation

A spectral-kinetic recorder operating in a special time-gating mode was developed for time-shifted measurement of time-resolved spectra and emission-line intensity kinetics in atomic emission analysis. The luminescence intensity kinetics of Cu, Zn, Sn, and Pb were recorded for two-pulse laser ablati...

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Veröffentlicht in:Journal of applied spectroscopy 2019-05, Vol.86 (2), p.294-299
Hauptverfasser: Voropay, E. S., Ermalitskaia, K. F., Ermalitskii, F. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:A spectral-kinetic recorder operating in a special time-gating mode was developed for time-shifted measurement of time-resolved spectra and emission-line intensity kinetics in atomic emission analysis. The luminescence intensity kinetics of Cu, Zn, Sn, and Pb were recorded for two-pulse laser ablation of pure metals and multicomponent alloys. The spectral-line intensity kinetics of pure metals could be approximated with high accuracy by exponential functions. The analytical signal for ablation of multicomponent samples decayed exponentially only for interpulse laser intervals
ISSN:0021-9037
1573-8647
DOI:10.1007/s10812-019-00815-3