Synthesis of anabasine-containing aminomethyl derivatives of 6-hydroxyaurones

Synthesis of anabasine-containing aminomethyl derivatives of 6-hydroxyaurones

Aminomethylation of aurones was studied by using anabasine. The reaction in the case of 6-hydroxyaurones was shown to selectively provide 7-aminomethyl-6-hydroxyaurones, while 5-aminomethyl-6-hydroxy-7-methylaurones could be obtained by transamination of 5-dimethylaminomethyl derivatives of 6-hydrox...

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Veröffentlicht in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2019-03, Vol.55 (3), p.212-216
Hauptverfasser: Popova, Antonina V., Bondarenko, Svitlana P., Vinogradova, Valentina I., Frasinyuk, Mykhaylo S.
Format: Artikel
Sprache:eng
Schlagworte:
Alkaloids
Chemistry
Chemistry and Materials Science
Derivatives
Organic Chemistry
Pharmacy
Pyridine
Technology
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Zusammenfassung:Aminomethylation of aurones was studied by using anabasine. The reaction in the case of 6-hydroxyaurones was shown to selectively provide 7-aminomethyl-6-hydroxyaurones, while 5-aminomethyl-6-hydroxy-7-methylaurones could be obtained by transamination of 5-dimethylaminomethyl derivatives of 6-hydroxy-7-methylaurones in the presence of anabasine.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-019-02444-2