High-Performance MIM Capacitors Using Zr-Sn-Ti-O Dielectrics Derived from Atomic Layer Deposition

Metal-insulator-metal (MIM) capacitors fabricated with Zr-Sn-Ti-O dielectrics by the plasma-enhanced atomic layer deposition (PEALD) were first demonstrated. By changing the pulse cycle ratio and cycle number of PEALD, the comprehensive electrical properties of the Zr-Sn-Ti-O MIM capacitors were opt...

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Veröffentlicht in:IEEE electron device letters 2019-05, Vol.40 (5), p.682-685
Hauptverfasser: Fang, Chang, Wang, Mei, Han, Ping, Cao, Yan-Qiang, Wu, Di, Li, Ai-Dong
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container_issue 5
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creator Fang, Chang
Wang, Mei
Han, Ping
Cao, Yan-Qiang
Wu, Di
Li, Ai-Dong
description Metal-insulator-metal (MIM) capacitors fabricated with Zr-Sn-Ti-O dielectrics by the plasma-enhanced atomic layer deposition (PEALD) were first demonstrated. By changing the pulse cycle ratio and cycle number of PEALD, the comprehensive electrical properties of the Zr-Sn-Ti-O MIM capacitors were optimized to meet the requirements of system-level chips for the high-density MIM capacitors. When the cycle ratio of ZrO 2 :SnO 2 :TiO 2 is 2:10:2, the sample of Zr 0.45 Sn 0.06 Ti 0.48 O 2 shows the best electrical properties: a capacitance density of 10.8 fF/ \mu \text{m}^{{2}} , a quadratic voltage linearity of −83 ppm/V 2 , a leakage current density of 5\times 10^{{-7}} A/cm 2 at 3 V, a breakdown voltage of 6.8 V, and a temperature linearity coefficient of 95.1 ppm/°C. These results indicate that PEALD Zr-Sn-Ti-O dielectrics are promising candidates for future high-density MIM capacitor applications in radio frequency and analog-/mixed-signal integrated circuits.
doi_str_mv 10.1109/LED.2019.2907981
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By changing the pulse cycle ratio and cycle number of PEALD, the comprehensive electrical properties of the Zr-Sn-Ti-O MIM capacitors were optimized to meet the requirements of system-level chips for the high-density MIM capacitors. When the cycle ratio of ZrO 2 :SnO 2 :TiO 2 is 2:10:2, the sample of Zr 0.45 Sn 0.06 Ti 0.48 O 2 shows the best electrical properties: a capacitance density of 10.8 fF/<inline-formula> <tex-math notation="LaTeX">\mu \text{m}^{{2}} </tex-math></inline-formula>, a quadratic voltage linearity of −83 ppm/V 2 , a leakage current density of <inline-formula> <tex-math notation="LaTeX">5\times 10^{{-7}} </tex-math></inline-formula> A/cm 2 at 3 V, a breakdown voltage of 6.8 V, and a temperature linearity coefficient of 95.1 ppm/°C. 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subjects Analog circuits
Atomic layer epitaxy
Capacitance
Capacitors
Cycle ratio
Dielectrics
Electric potential
Electrical properties
High-k dielectric materials
Integrated circuits
Leakage current
Leakage currents
Linearity
MIM capacitors
PEALD
Tin dioxide
Titanium
Titanium dioxide
Zirconium dioxide
Zr-Sn-Ti-O
title High-Performance MIM Capacitors Using Zr-Sn-Ti-O Dielectrics Derived from Atomic Layer Deposition
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