Hydroprocessing of Vacuum Gas Oil on NiMo Sulfide Catalyst Supported on an Ordered Mesoporous Polymer
The MPF-NiMoS catalyst prepared in situ by decomposition of the thio salt [N( n -Bu) 4 ] 2 [Ni(MoS 4 ) 2 ] in pores of an ordered mesoporous phenol-formaldehyde polymer was tested in hydroprocessing of vacuum gas oil in a batch reactor at 380–420°C and a pressure of 5.0 MPa for 5 h. The mean length...
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Veröffentlicht in: | Russian journal of applied chemistry 2019-02, Vol.92 (2), p.300-303 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The MPF-NiMoS catalyst prepared in situ by decomposition of the thio salt [N(
n
-Bu)
4
]
2
[Ni(MoS
4
)
2
] in pores of an ordered mesoporous phenol-formaldehyde polymer was tested in hydroprocessing of vacuum gas oil in a batch reactor at 380–420°C and a pressure of 5.0 MPa for 5 h. The mean length of sulfide nanoparticles is 4.2 nm, and the mean number of layers is 2. The fraction of lighter products and the degree of desulfurization increase with temperature. |
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ISSN: | 1070-4272 1608-3296 |
DOI: | 10.1134/S1070427219020204 |