Influence of low temperature truncated calorimetric data on the determination of the magnetocaloric effect of biphasic materials
•Low temperature limit of heat capacity affects the calculated magnetocaloric effect.•There is an initial temperature that minimizes the errors in the calculation.•This is valid for first and second order phase transitions.•The demonstration is extended to materials with two non-interacting magnetic...
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Veröffentlicht in: | Journal of magnetism and magnetic materials 2019-06, Vol.479, p.236-239 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •Low temperature limit of heat capacity affects the calculated magnetocaloric effect.•There is an initial temperature that minimizes the errors in the calculation.•This is valid for first and second order phase transitions.•The demonstration is extended to materials with two non-interacting magnetic phases.
It has recently been found that, for single phase materials, the truncation of the low temperature part of heat capacity curves produces a non-monotonic temperature dependent error in the calculated specific isothermal entropy change (ΔsT) and adiabatic temperature change (ΔTS). However, it was demonstrated that there is a certain initial temperature for which the errors are zero, regardless of the order of the phase transition. This work extends the demonstration to materials with two non-interacting magnetic phases. It is shown that there exists a temperature region close to the transition temperature of one phase for which the truncation of the curves produce a large error in the calculated ΔsT and ΔTS. Away from the vicinity of the phase transition of the phases, it is possible to minimize the errors of the results by choosing a specific initial temperature for integration. A systematic study of the influence of the phase fraction of the secondary phase and distance between transition temperatures is presented. |
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ISSN: | 0304-8853 1873-4766 |
DOI: | 10.1016/j.jmmm.2019.02.033 |