Investigation of the Diastomerism of Compounds with a Long-Chain Tether between the Stereogenic Centers

The NMR spectra of several heterocyclic compounds synthesized at Omsk universities revealed manifestation of a diasteomerism at a large (up to fifteen bonds) distance between the stereogenic centers. This phenomenon was explained by a regular helical secondary structure of the tether between the cen...

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Veröffentlicht in:	Russian journal of organic chemistry 2019-02, Vol.55 (2), p.161-167
Hauptverfasser:	Talsi, V. P., Evdokimov, S. N., Shatsauskas, A. L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Heterocyclic compounds NMR Nuclear magnetic resonance Organic Chemistry
Online-Zugang:	Volltext
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Zusammenfassung:	The NMR spectra of several heterocyclic compounds synthesized at Omsk universities revealed manifestation of a diasteomerism at a large (up to fifteen bonds) distance between the stereogenic centers. This phenomenon was explained by a regular helical secondary structure of the tether between the centers.
ISSN:	1070-4280 1608-3393
DOI:	10.1134/S1070428019020064