Electronic energy transfer studied by many-body Green’s function theory

We present a combination of many-body Green’s function theory and Förster-Dexter theory to estimate the excitation energy transfer (EET) coupling in both the isolated and condensed systems. This approach employs the accurate wave functions of excitons, which are derived from the Bethe-Salpeter equat...

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Veröffentlicht in:The Journal of chemical physics 2019-04, Vol.150 (16), p.164107-164107
Hauptverfasser: Leng, Xia, Jin, Fan, Wei, Min, Ma, Huizhong, Feng, Jin, Ma, Yuchen
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Sprache:eng
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Zusammenfassung:We present a combination of many-body Green’s function theory and Förster-Dexter theory to estimate the excitation energy transfer (EET) coupling in both the isolated and condensed systems. This approach employs the accurate wave functions of excitons, which are derived from the Bethe-Salpeter equation, in the donor and acceptor to set up the electronic coupling terms. Dexter coupling, which arises from the exchange-correlation effect, is evaluated based on the GW method which is a state-of-the-art ab initio theory for the description of self-energy. This approach is applicable to various situations, especially for periodic systems. The approach is tested on some model molecular dimers and compared with other high-level quantum chemistry methods together with the exact supermolecule scheme. Finally, we apply it to study the EET between periodic single-walled carbon nanotubes, exploring the dependence of EET on the chirality of nanotubes and the type of excitation transferred, finding that dark states play key roles in the EET between nanotubes. The EET rate falls as ∼D−12 approximately with the distance D between nanotubes for small D, much faster than the traditional Förster model.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.5066290