Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability

Mononuclear complexes (3-XPyH)[SbBr 6 ] (X = Cl ( I ), Br ( II )) are synthesized by the reactions of Sb 2 O 3 , Br 2 , and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability o...

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Veröffentlicht in:	Russian journal of coordination chemistry 2019-02, Vol.45 (2), p.128-132
Hauptverfasser:	Adonin, S. A., Bondarenko, M. A., Abramov, P. A., Korolkov, I. V., Plyusnin, P. E., Sokolov, M. N., Fedin, V. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Chemistry Chemistry and Materials Science Crystal structure Crystals Inorganic Chemistry Physical Chemistry Structural analysis Structural stability Thermal stability Thermogravimetry
Online-Zugang:	Volltext
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Zusammenfassung:	Mononuclear complexes (3-XPyH)[SbBr 6 ] (X = Cl ( I ), Br ( II )) are synthesized by the reactions of Sb 2 O 3 , Br 2 , and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability of the synthesized complexes is studied by thermogravimetry.
ISSN:	1070-3284 1608-3318
DOI:	10.1134/S1070328419020027