High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide

High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide

The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N -phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of act...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of organic chemistry 2019, Vol.55 (1), p.7-10
Hauptverfasser: Kornilov, D. A., Kiselev, V. D., Anikin, O. V., Kolesnikova, A. O., Shulyat’ev, A. A.
Format: Artikel
Sprache:eng
Schlagworte:
Acceleration
Chemistry
Chemistry and Materials Science
Cycloaddition
Diels-Alder reactions
Organic Chemistry
Pressure effects
Solvent effect
Solvents
Temperature effects
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N -phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of activation and reaction coincided within the experimental error, in keeping with the presumed cyclic transition state.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428019010020