Enantioselective Hydrogenation of Ketones using Different Metal Complexes with a Chiral PNP Pincer Ligand

The synthesis of different metal pincer complexes coordinating to the chiral PNP ligand bis(2‐((2R,5R)‐2,5‐dimethyl‐phospholanoethyl))amine is described in detail. The characterized complexes with Mn, Fe, Re and Ru as metal centers showed good activities regarding the reduction of several prochiral...

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Veröffentlicht in:	Advanced synthesis & catalysis 2019-04, Vol.361 (8), p.1913-1920
Hauptverfasser:	Garbe, Marcel, Wei, Zhihong, Tannert, Bianca, Spannenberg, Anke, Jiao, Haijun, Bachmann, Stephan, Scalone, Michelangelo, Junge, Kathrin, Beller, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Asymmetric Catalysis Asymmetric Hydrogenation Chiral Alcohols Chiral Pincer Coordination compounds Enantiomers Iron Ketones Ligands Manganese Noble metals Prochiral Ketones Selectivity Substrates
Online-Zugang:	Volltext
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