Borohydride as Magnetic Superexchange Pathway in Late Lanthanide Borohydrides
The magnetic characteristics of a series of borohydride‐based systems, including binary α‐/β‐Ln(BH4)3 phases (Ln = Gd, Tb, Dy, Ho, Er, and Tm) with direct Ln–HBH–Ln bridges and selected mixed‐metal systems, LiYb(BH4)4, NaYb(BH4)4, KHo(BH4)4, RbTm(BH4)4, with isolated Ln3+ ions embedded in [Ln(BH4)4]...
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Veröffentlicht in: | European journal of inorganic chemistry 2019-04, Vol.2019 (13), p.1776-1783 |
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Sprache: | eng |
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Zusammenfassung: | The magnetic characteristics of a series of borohydride‐based systems, including binary α‐/β‐Ln(BH4)3 phases (Ln = Gd, Tb, Dy, Ho, Er, and Tm) with direct Ln–HBH–Ln bridges and selected mixed‐metal systems, LiYb(BH4)4, NaYb(BH4)4, KHo(BH4)4, RbTm(BH4)4, with isolated Ln3+ ions embedded in [Ln(BH4)4]– anions are described for the first time using SQUID magnetometry and DFT+U calculations. Crystal field effects as well as the nature and strength of magnetic superexchange interactions via BH4– ligands are established based on a ligand field theory approach. We find Auzel's scalar crystal field strength parameter (Nv, the weighted quadratic mean of the ligand field parameters Bkq) for these systems to be substantial, in particular for α‐Ho(BH4)3, indicating a significant covalent component in the Ho···H bonding. The BH4– anion is capable of mediating both weakly ferro‐ or antiferromagnetic superexchange. Quantum mechanical DFT+U calculations, even when including spin‐orbit coupling effects, do not reliably describe the sign and the size of the magnetic superexchange constants in these systems.
In contrast to its “smaller brother”, the hydride anion, BH4– can transmit both ferromagnetic and antiferromagnetic coupling in lanthanide‐based borohydride phases, due to the crucial role of the boron 2p orbitals that are involved in the superexchange. In Ho3+, very high ligand field splitting is observed, suggesting a pronounced covalent component in Ho–H(BH3) bonds. |
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ISSN: | 1434-1948 1099-0682 |
DOI: | 10.1002/ejic.201801488 |