Sol–gel mediated microwave synthesis of pure, La and Zr doped SnS2 nanoflowers an efficient photocatalyst for the degradation of methylene blue

La and Zr intercalated SnS 2 nanostructures have been synthesised using facile sol–gel mediated microwave method. Photocatalytic activity of methylene blue dye was investigated using the synthesized nanosturctures and superior photocatalytic activity was witnessed for the La and Zr intercalated SnS...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2019-04, Vol.30 (8), p.7963-7973
Hauptverfasser: Govindan, V., Kashinath, L., Joseph Daniel, D., Sankaranarayanan, K.
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Sprache:eng
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Zusammenfassung:La and Zr intercalated SnS 2 nanostructures have been synthesised using facile sol–gel mediated microwave method. Photocatalytic activity of methylene blue dye was investigated using the synthesized nanosturctures and superior photocatalytic activity was witnessed for the La and Zr intercalated SnS 2 than the pure SnS 2 nanoflower. It is attributed to the enhanced surface charge carriers and fast electron transport inside the lattice of SnS 2 . Enlargement on surface active sites in turn increases surface absorption effect due to La and Zr which acts as tentacles to control the recombination process and promotes the higher photoredox reaction. The synthesized nanomaterials were characterized using PXRD, Raman, PL, UV–Vis spectroscopy, FE-SEM and XPS. It is noted from the structural analysis that the decrease in cell volume with increase of doping concentration contributes to Moss-Burstein effect. The increment of band gap and quenching in the photoluminescence effect supported the absorptivity of photoenergies which served as photosensitizer.
ISSN:0957-4522
1573-482X
DOI:10.1007/s10854-019-01117-2