Sorption and photodegradation under visible light irradiation of an organic pollutant by a heterogeneous UiO-67-Ru-Ti MOF obtained by post-synthetic exchange
The synthesis of a UiO-67 based MOF was made through the combination of two synthetic pathways, first a solvothermal synthesis in the presence of two different linkers, one for the structure and one to work as a light antenna (based on Ru), followed by a process of post-synthetic metal exchange on t...
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Veröffentlicht in: | RSC advances 2017-01, Vol.7 (1), p.195-2 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The synthesis of a UiO-67 based MOF was made through the combination of two synthetic pathways, first a solvothermal synthesis in the presence of two different linkers, one for the structure and one to work as a light antenna (based on Ru), followed by a process of post-synthetic metal exchange on the coordination node to include a catalyst (Ti). This MOF has been able to remove an organic pollutant from an aqueous solution and to catalyze the degradation of the pollutant under visible light irradiation.
By exchanging metals in a photoactive MOF, it has been possible to obtain a material for the photodegradation of methylene blue. |
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ISSN: | 2046-2069 2046-2069 |
DOI: | 10.1039/c6ra26552a |