An investigation of (C^sub 5^H^sub 5^)Fe(C^sub 5^H^sub 4^-C(OBF^sub 3^)-CH^sub 3^)

Acetylferrocene readily forms an adduct with BF... The product is a neutral model for protonated acetylferrocene, a species that is a crucial intermediate in the formation of 1,3,5-trisferrocenyl-benzene and other conjugated heterometallic derivatives by cyclocondensation. The title compound's...

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Veröffentlicht in:Canadian journal of chemistry 2009-07, Vol.87 (7), p.1055
Hauptverfasser: Ogini, Francis O, Elder, Philip J W, Britten, James F, Vargas-Baca, Ignacio
Format: Artikel
Sprache:eng
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Zusammenfassung:Acetylferrocene readily forms an adduct with BF... The product is a neutral model for protonated acetylferrocene, a species that is a crucial intermediate in the formation of 1,3,5-trisferrocenyl-benzene and other conjugated heterometallic derivatives by cyclocondensation. The title compound's structure was determined in the solid state by X-ray diffraction and its spectroscopic properties were examined in detail, particularly the electronic excitation spectrum, which confirms the previous identification of the in situ generated protonated ketone. (ProQuest: ... denotes formulae/symbols omitted.)
ISSN:0008-4042
1480-3291