The addition of alkynes to a tetrasilyldisilene - Evidence for a biradical intermediate1

The addition of two newly developed mechanistic probes, (trans,trans-2-methoxy-3-phenylcyclopropyl)ethyne (1) and (trans,trans-2-methoxy-1-methyl-3-phenylcyclopropyl)ethyne (2), to tetrakis(tert-butyldimethylsilyl)disilene (3) has been investigated. The addition of 1 to 3 gave 1-[2-(cis-2-methoxy-3-phenylcyclopropylidene)vinyl]-1,1,2,2-tetrakis(tert-butyldimethylsilyl)disilane (5) as the major product; whereas addition of alkyne 2 to the disilene gave three stereoisomers of 1,1,2,2-tetrakis(tert-butyldimethylsilyl)-6-methoxy-5-methyl-7-phenyl-1,2-disilacyclohepta-3,4-diene (7-9) and 1,1,2,2-tetrakis(tert-butyldimethylsilyl)-3-(trans,trans-2-methoxy-1-methyl-3-phenylcyclopropyl)-1,2-disilacyclobut-3-ene (10) as the major products. The formation of cycloheptaallenes 7-9 provides convincing evidence that the addition of alkynes to tetrasilyldisilenes involves the formation of a biradical intermediate. [PUBLICATION ABSTRACT]