Reactivity in acid-catalyzed carbon-carbon heterolysis

Reactivity in acid-catalyzed carbon-carbon heterolysis

Equlibrium and rate constants have been determined for the acid-catalyzed heterolysis of two alcohols, 9-xanthydrol and p-anisyldiphenylmethanol, and two sulfides, (9-xanthyl) methyl sulfide and (7-tropyl) methyl sulfide.

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Veröffentlicht in:Canadian journal of chemistry 1999-05, Vol.77 (5-6), p.1009-1034
Hauptverfasser: Cao, Weiguo, Erden, Ihsan, Grow, Richard H., Keeffe, James R., Song, Jiangao, Trudell, Mary B., Wadsworth, Teri L., Xu, Fu-Pei, Zheng, Ji-Bin
Format: Artikel
Sprache:eng
Schlagworte:
Carbon
Chemical bonds
Chemistry
Equilibrium
Heterolysis
Hydroxy compounds
Ions
Sulfides
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Zusammenfassung:Equlibrium and rate constants have been determined for the acid-catalyzed heterolysis of two alcohols, 9-xanthydrol and p-anisyldiphenylmethanol, and two sulfides, (9-xanthyl) methyl sulfide and (7-tropyl) methyl sulfide.
ISSN:0008-4042
1480-3291
DOI:10.1139/cjc-77-5-6-1009