Rhodium-catalyzed hydroborations of allylamine and allylimines

Rhodium-catalyzed hydroborations of allylamine and allylimines

The in situ rhodium-catalyzed addition of catecholborane (HBcat, cat = 1,2-O2C6H4) and pinacolborane (HBpin, pin = 1,2-O2C2Me4) to allylamine, allylimine, 2- and 4-vinylpyridines, and a thienyl imine has been examined using multinuclear NMR spectroscopy. The first examples of metal-catalyzed hydrobo...

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Veröffentlicht in:Canadian journal of chemistry 2001-12, Vol.79 (12), p.1898
Hauptverfasser: Vogels, Christopher M, O'Connor, Paul E, Phillips, Trevor E, Watson, Keith J
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Rhodium
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Zusammenfassung:The in situ rhodium-catalyzed addition of catecholborane (HBcat, cat = 1,2-O2C6H4) and pinacolborane (HBpin, pin = 1,2-O2C2Me4) to allylamine, allylimine, 2- and 4-vinylpyridines, and a thienyl imine has been examined using multinuclear NMR spectroscopy. The first examples of metal-catalyzed hydroboration of imines using HBpin are also reported.
ISSN:0008-4042
1480-3291
DOI:10.1139/v01-177