Alternating copolymerization of omega-perfluoroaklyl-1-alkenes with carbon monoxide catalyzed by homogeneous and polymer-supported Pd-complexes

Alternating copolymerization of omega-perfluoroaklyl-1-alkenes with carbon monoxide catalyzed by homogeneous and polymer-supported Pd-complexes

Alternating copolymerization of fluroinated olefins (CnF2n+1)(CH2)mCH=CH2 (1) and carbon monoxide was carried out using cationic Pd(II)-(R,S)-BINAPHOS complexes (2) as catalysts. To obtain polymeric products sufficiently, existence of at least two methylenes in 1 were essential (m >==2).

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Veröffentlicht in:Canadian journal of chemistry 2001-05, Vol.79 (5/6), p.593
Hauptverfasser: Nozaki, Kyoko, Shibahara, Fumitoshi, Elzner, Stephan, Hiyama, Tamejiro
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Analysis
Carbon monoxide
Catalysts
Polymers
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Zusammenfassung:Alternating copolymerization of fluroinated olefins (CnF2n+1)(CH2)mCH=CH2 (1) and carbon monoxide was carried out using cationic Pd(II)-(R,S)-BINAPHOS complexes (2) as catalysts. To obtain polymeric products sufficiently, existence of at least two methylenes in 1 were essential (m >==2).
ISSN:0008-4042
1480-3291