New syntheses of dillapiol [4,5-dimetho×y-6-(2-propenyl)-1,3-benzodio×ole], its 4-methylthio and other analogs

Three syntheses of the natural synergist dillapiol from the natural, commercially available sesamol as starting material, are described. A major difference between these is the order of introduction of the additional methoxy and allyl substituents.

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Veröffentlicht in:Canadian journal of chemistry 2000-10, Vol.78 (10), p.1345-1355
Hauptverfasser: Majerus, Sherry L., Alibhai, Najma, Tripathy, Sasmita, Durst, Tony
Format: Artikel
Sprache:eng
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Zusammenfassung:Three syntheses of the natural synergist dillapiol from the natural, commercially available sesamol as starting material, are described. A major difference between these is the order of introduction of the additional methoxy and allyl substituents.
ISSN:0008-4042
1480-3291
DOI:10.1139/cjc-78-10-1345