Organic reaction in water. Part 2: Michael addition in water without phase transfer agents

Organic reaction in water. Part 2: Michael addition in water without phase transfer agents

The Michael additions of dicarbonyl compounds, nitroalkanes, and thiols to 2-cyclohexen-1-one can be accomplished in water without phase transfer agents. The reaction is extremely sensitive to the pH of the reaction media, and therefore, the methodology can be optimized with the control of this vari...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Canadian journal of chemistry 1999-05, Vol.77 (5-6), p.624-627
Hauptverfasser: da Silva, Flavia Martins, Gomes, Adriana Kniaseff, Jones, Jr, Joel
Format: Artikel
Sprache:eng
Schlagworte:
Addition (Chemistry)
Chemical reactions
Chemistry
Ketones
Nitrogen compounds
Solvents
Water
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The Michael additions of dicarbonyl compounds, nitroalkanes, and thiols to 2-cyclohexen-1-one can be accomplished in water without phase transfer agents. The reaction is extremely sensitive to the pH of the reaction media, and therefore, the methodology can be optimized with the control of this variable.
ISSN:0008-4042
1480-3291
DOI:10.1139/cjc-77-5-6-624