Sonochemical driven simple preparation of nitrogen-doped carbon quantum dots/SnO2 nanocomposite: A novel electrocatalyst for sensitive voltammetric determination of riboflavin

[Display omitted] •N-CQD/SnO2 nanocomposite was prepared using sonochemical approach for first time.•N-CQD/SnO2 nanocomposite modified electrode exhibits sensitive electrochemical reaction towards riboflavin.•Modified electrode shows wide linear range and very low detection limit. We report a simple...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2019-02, Vol.281, p.602-612
Hauptverfasser: Muthusankar, Ganesan, Rajkumar, Chellakannu, Chen, Shen-Ming, Karkuzhali, Rajendran, Gopu, Gopalakrishnan, Sangili, Arumugam, Sengottuvelan, Nallathambi, Sankar, Raman
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Sprache:eng
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Zusammenfassung:[Display omitted] •N-CQD/SnO2 nanocomposite was prepared using sonochemical approach for first time.•N-CQD/SnO2 nanocomposite modified electrode exhibits sensitive electrochemical reaction towards riboflavin.•Modified electrode shows wide linear range and very low detection limit. We report a simple preparation of novel nanocomposite for the sensitive determination of riboflavin (RF) in real samples. Nitrogen-doped carbon quantum dots/SnO2 (N-CQD/SnO2) nanocomposite was prepared using sonochemical approach and applied as a voltammetric sensor for the sensitive determination of RF for the first time. The crystallographic phase, functional groups, surface analysis, and elemental distribution were examined using XRD, FT-IR, HR-TEM and EDS spectroscopic techniques respectively. This N-CQD/SnO2 nanocomposite-modified electrode shows a fast and sensitive electrochemical response to RF sensing with a good sensitivity (2.496 μA μM−1 cm-2), wide linear range (0.05–306 μM), low detection limit (8 nM) and excellent anti-interference ability. Furthermore, the developed sensor was investigated in commercial riboflavin tablets and milk powder and obtained results are quite satisfactory.
ISSN:0925-4005
1873-3077
DOI:10.1016/j.snb.2018.10.145