Green synthesis of 1,2,3‐triazoles via Cu2O NPs on hydrogen trititanate nanotubes promoted 1,3‐dipolar cycloadditions
Cu2O nanoparticles supported on hydrogen trititanate nanotubes (Cu2O/HTNT) catalysts have been efficiently catalyzed the multicomponent synthesis of 1,2,3‐triazoles in water at room temperature from different azide precursors, for example organic halides, sulfonates and anilines. The catalysts were...
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creator | Bhoomireddy, Rajendra Prasad Reddy Narla, L.G. Bhavani Peddiahgari, Vasu Govardhana Reddy |
description | Cu2O nanoparticles supported on hydrogen trititanate nanotubes (Cu2O/HTNT) catalysts have been efficiently catalyzed the multicomponent synthesis of 1,2,3‐triazoles in water at room temperature from different azide precursors, for example organic halides, sulfonates and anilines. The catalysts were synthesized by hydrothermal & wet‐impregnation methods and was characterized by HR‐TEM, EDS, XRD, XPS, N2‐adsorption desorption and ICP‐MS analysis. The catalyst could be recycled by centrifugation and reused up to seven cycles. The 1‐benzyl‐4‐(4‐chlorophenyl)‐1H‐1,2,3‐triazole (25) structure was proven by single crystal X‐ray diffraction studies.
An efficient Cu2O nanoparticles/hydrogen trititanate nanotubes catalyzed 1,2,3‐triazoles has been achieved through one pot azidation/1,3 dipolar cycloaddition of in situ generated azides and alkynes in water. |
doi_str_mv | 10.1002/aoc.4752 |
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An efficient Cu2O nanoparticles/hydrogen trititanate nanotubes catalyzed 1,2,3‐triazoles has been achieved through one pot azidation/1,3 dipolar cycloaddition of in situ generated azides and alkynes in water.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.4752</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>alkynes, copper nanoparticles, hydrogen trititanate nanotubes, multicomponent reactions, triazoles ; Catalysis ; Catalysts ; Chemical synthesis ; Chemistry ; Copper oxides ; Crystal structure ; Crystals ; Halides ; Nanoparticles ; Nanotubes ; Single crystals ; Sulfonates ; Triazoles ; X ray photoelectron spectroscopy ; X-ray diffraction</subject><ispartof>Applied organometallic chemistry, 2019-03, Vol.33 (3), p.n/a</ispartof><rights>2018 John Wiley & Sons, Ltd.</rights><rights>2019 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-8837-0847</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.4752$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.4752$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Bhoomireddy, Rajendra Prasad Reddy</creatorcontrib><creatorcontrib>Narla, L.G. Bhavani</creatorcontrib><creatorcontrib>Peddiahgari, Vasu Govardhana Reddy</creatorcontrib><title>Green synthesis of 1,2,3‐triazoles via Cu2O NPs on hydrogen trititanate nanotubes promoted 1,3‐dipolar cycloadditions</title><title>Applied organometallic chemistry</title><description>Cu2O nanoparticles supported on hydrogen trititanate nanotubes (Cu2O/HTNT) catalysts have been efficiently catalyzed the multicomponent synthesis of 1,2,3‐triazoles in water at room temperature from different azide precursors, for example organic halides, sulfonates and anilines. The catalysts were synthesized by hydrothermal & wet‐impregnation methods and was characterized by HR‐TEM, EDS, XRD, XPS, N2‐adsorption desorption and ICP‐MS analysis. The catalyst could be recycled by centrifugation and reused up to seven cycles. The 1‐benzyl‐4‐(4‐chlorophenyl)‐1H‐1,2,3‐triazole (25) structure was proven by single crystal X‐ray diffraction studies.
An efficient Cu2O nanoparticles/hydrogen trititanate nanotubes catalyzed 1,2,3‐triazoles has been achieved through one pot azidation/1,3 dipolar cycloaddition of in situ generated azides and alkynes in water.</description><subject>alkynes, copper nanoparticles, hydrogen trititanate nanotubes, multicomponent reactions, triazoles</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Copper oxides</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Halides</subject><subject>Nanoparticles</subject><subject>Nanotubes</subject><subject>Single crystals</subject><subject>Sulfonates</subject><subject>Triazoles</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNotkEFOwzAURC0EEqUgcQRLbJtiO44dL6sIClJFWcA6cmKHpkrtYDugsOIInJGT4KisZvPm_a8B4BqjJUaI3EpbLynPyAmYYSREgngqTsEMEZYnhKHsHFx4v0cICYbpDIxrp7WBfjRhp33roW0gXpBF-vv9E1wrv2ynPfxoJSwGsoVPz5EwcDcqZ99iLyKhDdLIoKGRxoahinjv7MEGraJp8qi2t510sB7rzkqlYsUafwnOGtl5ffWfc_B6f_dSPCSb7fqxWG2SHmeYJBRJ1VSiYRlVpGay4bxRQqcNqxkjSmCd81pxypVgQlFecZRJniGZNnlVM5rOwc3RG796H7QP5d4OzsSTJcF5SmlGhYhUcqQ-206PZe_ag3RjiVE5rVrGVctp1XK1LaZM_wCrTW6s</recordid><startdate>201903</startdate><enddate>201903</enddate><creator>Bhoomireddy, Rajendra Prasad Reddy</creator><creator>Narla, L.G. Bhavani</creator><creator>Peddiahgari, Vasu Govardhana Reddy</creator><general>Wiley Subscription Services, Inc</general><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-8837-0847</orcidid></search><sort><creationdate>201903</creationdate><title>Green synthesis of 1,2,3‐triazoles via Cu2O NPs on hydrogen trititanate nanotubes promoted 1,3‐dipolar cycloadditions</title><author>Bhoomireddy, Rajendra Prasad Reddy ; Narla, L.G. Bhavani ; Peddiahgari, Vasu Govardhana Reddy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1512-40adfb9f654d2c6af77fd9e3f6c662d91e87cd747d969d47b705a750a3f8bc643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>alkynes, copper nanoparticles, hydrogen trititanate nanotubes, multicomponent reactions, triazoles</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Copper oxides</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Halides</topic><topic>Nanoparticles</topic><topic>Nanotubes</topic><topic>Single crystals</topic><topic>Sulfonates</topic><topic>Triazoles</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bhoomireddy, Rajendra Prasad Reddy</creatorcontrib><creatorcontrib>Narla, L.G. Bhavani</creatorcontrib><creatorcontrib>Peddiahgari, Vasu Govardhana Reddy</creatorcontrib><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bhoomireddy, Rajendra Prasad Reddy</au><au>Narla, L.G. Bhavani</au><au>Peddiahgari, Vasu Govardhana Reddy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green synthesis of 1,2,3‐triazoles via Cu2O NPs on hydrogen trititanate nanotubes promoted 1,3‐dipolar cycloadditions</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2019-03</date><risdate>2019</risdate><volume>33</volume><issue>3</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>Cu2O nanoparticles supported on hydrogen trititanate nanotubes (Cu2O/HTNT) catalysts have been efficiently catalyzed the multicomponent synthesis of 1,2,3‐triazoles in water at room temperature from different azide precursors, for example organic halides, sulfonates and anilines. The catalysts were synthesized by hydrothermal & wet‐impregnation methods and was characterized by HR‐TEM, EDS, XRD, XPS, N2‐adsorption desorption and ICP‐MS analysis. The catalyst could be recycled by centrifugation and reused up to seven cycles. The 1‐benzyl‐4‐(4‐chlorophenyl)‐1H‐1,2,3‐triazole (25) structure was proven by single crystal X‐ray diffraction studies.
An efficient Cu2O nanoparticles/hydrogen trititanate nanotubes catalyzed 1,2,3‐triazoles has been achieved through one pot azidation/1,3 dipolar cycloaddition of in situ generated azides and alkynes in water.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.4752</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-8837-0847</orcidid></addata></record> |
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subjects | alkynes, copper nanoparticles, hydrogen trititanate nanotubes, multicomponent reactions, triazoles Catalysis Catalysts Chemical synthesis Chemistry Copper oxides Crystal structure Crystals Halides Nanoparticles Nanotubes Single crystals Sulfonates Triazoles X ray photoelectron spectroscopy X-ray diffraction |
title | Green synthesis of 1,2,3‐triazoles via Cu2O NPs on hydrogen trititanate nanotubes promoted 1,3‐dipolar cycloadditions |
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