Crystalline Copper Phosphates: Synthesis and Thermal Stability

The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid‐state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(...

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Veröffentlicht in:	Journal of the American Ceramic Society 1997-12, Vol.80 (12), p.3133-3138
Hauptverfasser:	Bamberger, Carlos E., Specht, E. D., Anovitz, Lawrence M.
Format:	Artikel
Sprache:	eng
Schlagworte:	BORON PHOSPHATES CHEMICAL COMPOSITION Chemistry COPPER OXIDES COPPER PHOSPHATES DECOMPOSITION Exact sciences and technology Inorganic chemistry and origins of life MATERIALS SCIENCE Preparations and properties Salts SYNTHESIS THERMODYNAMIC PROPERTIES
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Zusammenfassung:	The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid‐state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.
ISSN:	0002-7820 1551-2916
DOI:	10.1111/j.1151-2916.1997.tb03241.x