New parameters for the characterization of relationship between gas chromatographic retention and temperature

Parameters T(ik) and of other parameters derived from them by principal component analysis can be used to characterize the relationship between capacity ration (k) and temperature (T) for any compound/column pair. These parameters can also be used as a starting point for the calculation of gas chrom...

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Veröffentlicht in:	Analytical chemistry (Washington) 1993-10, Vol.65 (19), p.2643-2649
Hauptverfasser:	de Frutos, M, Sanz, J, Martinez-Castro, I, Jimenez, M. I
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Exact sciences and technology Gas chromatographic methods Gases
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Parameters T(ik) and of other parameters derived from them by principal component analysis can be used to characterize the relationship between capacity ration (k) and temperature (T) for any compound/column pair. These parameters can also be used as a starting point for the calculation of gas chromatographic retention and the optimization of separations.
ISSN:	0003-2700 1520-6882
DOI:	10.1021/ac00067a016