Surface Acoustic Wave Oxygen Sensor

A surface acoustic wave (SAW) device that responds to oxygen pressure was developed by coating a 158 MHz quartz surface acoustic wave (SAW) device with an oxygen binding agent. Two types of coatings were used. One type was prepared by dissolving an oxygen binding agent in a toluene solution of a cop...

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Veröffentlicht in:Analytical chemistry (Washington) 1994-09, Vol.66 (17), p.2745-2751
Hauptverfasser: Oglesby, Donald M, Upchurch, Billy T, Leighty, Bradley D, Collman, James P, Zhang, Xumu, Hermann, P. C
Format: Artikel
Sprache:eng
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Zusammenfassung:A surface acoustic wave (SAW) device that responds to oxygen pressure was developed by coating a 158 MHz quartz surface acoustic wave (SAW) device with an oxygen binding agent. Two types of coatings were used. One type was prepared by dissolving an oxygen binding agent in a toluene solution of a copolymer containing the axial ligand. A second type was prepared with an oxygen binding porphyrin solution containing excess axial ligand without a polymer matrix. In the polymer based coatings, the copolymer served to provide the axial ligand to the oxygen binding agent and as a coating matrix on the surface of the SAW device. The oxygen sensing SAW device has been shown to bind oxygen following a Langmuir isotherm and may be used to measure the equilibrium constant of the oxygen binding compound in the coating matrix.
ISSN:0003-2700
1520-6882
DOI:10.1021/ac00089a023