Multicomponent Determination of Chlorinated Hydrocarbons Using a Reaction-Based Chemical Sensor. 1. Multivariate Calibration of Fujiwara Reaction Products

Multicomponent Determination of Chlorinated Hydrocarbons Using a Reaction-Based Chemical Sensor. 1. Multivariate Calibration of Fujiwara Reaction Products

Multicomponent analysis for 1,1,1-trichloroethane, trichloroethylene and chloroform is demonstrated by partial least squares modeling absorbance data collected from the Fujiwara reaction of these analytes over time. Optimal calibration times are determined for each analyte dependent upon its reactio...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Analytical chemistry (Washington) 1994-10, Vol.66 (20), p.3328-3336
Hauptverfasser: Henshaw, John M, Burgess, Lloyd W, Booksh, Karl S, Kowalski, Bruce R
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Hydrocarbons
Sensors
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Multicomponent analysis for 1,1,1-trichloroethane, trichloroethylene and chloroform is demonstrated by partial least squares modeling absorbance data collected from the Fujiwara reaction of these analytes over time. Optimal calibration times are determined for each analyte dependent upon its reaction time.
ISSN:0003-2700
1520-6882
DOI:10.1021/ac00092a008