Labile hydrogen counting in biomolecules using deuterated reagents in desorption chemical ionization and fast atom bombardment mass spectrometry

In fast atom bombardment (FAB) experiments, a new procedure was developed that achieves high levels of deuterium substitution, avoids the risk of hydrogen/deuterium back-exchange with atmospheric water and allows the use of any water-soluble FAB matrix.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Analytical chemistry (Washington) 1992, Vol.64 (2), p.204-210
Hauptverfasser:	Guarini, Alessandro, Guglielmetti, Gianfranco, Andriollo, Nunzio, Vincenti, Marco
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical biochemistry: general aspects, technics, instrumentation Analytical, structural and metabolic biochemistry Atoms & subatomic particles Biological and medical sciences Chemical elements Chemistry Fundamental and applied biological sciences. Psychology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	In fast atom bombardment (FAB) experiments, a new procedure was developed that achieves high levels of deuterium substitution, avoids the risk of hydrogen/deuterium back-exchange with atmospheric water and allows the use of any water-soluble FAB matrix.
ISSN:	0003-2700 1520-6882
DOI:	10.1021/ac00026a021