Synthesis of Dimethyl Phenylphosphonates Catalyzed by Group VI Metal(0) Hexacarbonyls

Synthesis of Dimethyl Phenylphosphonates Catalyzed by Group VI Metal(0) Hexacarbonyls

The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.

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Veröffentlicht in:Russian journal of organic chemistry 2018-11, Vol.54 (11), p.1746-1748
Hauptverfasser: Kuramshin, A. I., Plotnikova, A. V., Adel’shina, M. V., Galkin, V. I.
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyls
Catalysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chromium
Coordination compounds
Organic Chemistry
Short Communications
Subgroups
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Beschreibung
Zusammenfassung:The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428018110234