Redox-controlled generation of the giant porphyry Cu–Au deposit at Pulang, southwest China

Some porphyry Cu–Au deposits with relatively reduced ore assemblages, characterized by high hydrothermal pyrrhotite contents and a lack of primary hematite and magnetite, are generally considered to be associated with reduced I-type granitoids. However, the role of magmatic oxygen fugacity ( f O 2 ) in controlling Cu–Au mineralization in such reduced porphyry deposits is poorly understood. The giant Late Triassic (ca 216 Ma) Pulang porphyry Cu–Au deposit of southwest China shows typical reduced ore assemblages. This study reported the systematical variation of upper crustal magmatic f O 2 of Pulang deposit, based on detailed investigations of mineral crystallization sequences and compositional features of the mineralization-related porphyries (early P1 and late P2 porphyry). Results indicate that magma of the mineralization-related porphyries experienced complex f O 2 fluctuations during its upper crustal evolution. The early primary magma had very high initial f O 2 , with ΔFMQ ≥ + 3.0 at depths of > 12 km [ΔFMQ is the deviation of log f O 2 from the fayalite–magnetite–quartz (FMQ) buffer]. The f O 2 of evolved parental magma subsequently decreased, with ΔFMQ ≤ + 1.9, due to injection of relatively reduced dioritic magmas (ΔFMQ = + 1.4 to + 2.3) from a deeper chamber (17–21 km depth) into the primary magma chamber at 10–12 km depth. Magma mixing had largely ceased at 6–10 km depth. The parental magma then ponded within the reduced Tumugou formation at a depth of ~ 3.7 km where magmatic f O 2 decreased to a moderately oxidized state (ΔFMQ = ~ + 1.6), and finally to a moderately reduced state [reflected by log(Fe 2 O 3 /FeO) ratios of − 0.5 for P2 porphyry]. Results of this study of magmatic f O 2 indicate that porphyry magmas associated with reduced Pulang ore assemblages were initially generated as highly oxidized magma which was subsequently reduced through magma mixing and contamination by reduced sedimentary rocks of the Tumugou Formation. The sharp f O 2 decrease at very shallow depth pr