Fabrication of innovative forward osmosis membranes via multilayered interfacial polymerization on electrospun nanofibers

ABSTRACT Practical application of forward osmosis (FO) membranes is beset by low water flux and vulnerability of selective polyamide (PA) layers. Herein, novel composite membranes were fabricated with multilayered PA via cyclic interfacial polymerization (IP) on electrospun polyethersulfone (PES) nanofiber substrates to realize high performance FO. The membrane fabrication conditions were optimized detailedly with respect to the morphologies, physicochemical properties, and FO performances. It is indicated that the PES concentration has great impacts on the morphology, thickness, and fiber diameter of the electrospun substrates and the optimal concentration is proved to be 26 wt %. After multilayered IP, the membrane thickness, surface hydrophilicity, and mechanical strength increased with IP cycles. The optimized FO membranes with two PA layers show much higher water flux and membrane selectivity compared with the commercial thin film composite membranes, holding great promise for water purification and seawater desalination. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47247. Preparation of innovative thin film compositie forword osmosis membrane.