Frontispiece: Planar‐Chiral Ferrocene‐Based N‐Heterocyclic Carbene Ligands

Frontispiece: Planar‐Chiral Ferrocene‐Based N‐Heterocyclic Carbene Ligands

N‐heterocyclic carbene (NHC) ligands are used frequently in in transition‐metal catalysis. As the basic shape of most classes of NHC rings is planar, it seems rational to employ a planar‐chiral element in the design of chiral NHC ligands. In their Minireview on page 18575 ff., K. Yoshida, R. Yasue d...

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Veröffentlicht in:Chemistry : a European journal 2018-12, Vol.24 (70), p.n/a
Hauptverfasser: Yoshida, Kazuhiro, Yasue, Risa
Format: Artikel
Sprache:eng
Schlagworte:
asymmetric catalysis
Catalysis
Chemistry
chiral ligands
ferrocene
Ligands
N-heterocyclic carbene
planar chirality
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Zusammenfassung:N‐heterocyclic carbene (NHC) ligands are used frequently in in transition‐metal catalysis. As the basic shape of most classes of NHC rings is planar, it seems rational to employ a planar‐chiral element in the design of chiral NHC ligands. In their Minireview on page 18575 ff., K. Yoshida, R. Yasue describe recent advances in chiral NHC ligands, focusing on planar‐chiral ferrocene‐based NHCs.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201887062