Fluid inclusion evidence for deep burial of the Tertiary accretionary wedge of the Carpathians

Hydrothermal quartz from mineralized joints of the Carpathian accretionary wedge contains immiscible aqueous, oil‐condensate, methane and carbon dioxide‐rich fluid inclusions. Distribution patterns of the inclusion trapping PT parameters point to a crack‐seal mechanism during upward and lateral migration of hot methane‐rich fluids from overpressured sediments at the base of the accretionary wedge. A simple equation is proposed to calculate depths from densities and trapping pressures of the buoyant inclusion fluids. In the Carpathian accretionary wedge, the paleofluid pressures of 52–306 MPa correspond to a 5‐ to 11‐km‐thick overburden. Prior to exhumation, thickness of the wedge must have attained 10–25 km, of which only c. 50% was preserved until recently. Anomalously high methane densities (up to 0.43 g cm−3) recorded in the lowermost nappe sheets are provisionally interpreted as a result of supralithostatic overpressure due to thermal cracking of oil and kerogen to methane and pyrobitumen at temperatures above 200 °C.