The Reactivity of Ferrocene and Its Derivatives in the Reaction with Quinines

The Reactivity of Ferrocene and Its Derivatives in the Reaction with Quinines

The reactivity of ferrocene derivatives with respect to p -quinones in acid media has been studied. A tentative mechanism of oxidation of ferrocene with p -qionone in acid media including two-step reduction of p-quinone to hydroquinone is proposed.

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Veröffentlicht in:Russian journal of general chemistry 2018-10, Vol.88 (10), p.2089-2095
Hauptverfasser: Fomin, V. M., Galkina, M. S., Klyuchevskii, K. V., Arsen’ev, M. V., Poddel’skii, A. I.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Derivatives
Hydroquinone
Iron compounds
Metallocenes
Oxidation
Quinone
Quinones
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Zusammenfassung:The reactivity of ferrocene derivatives with respect to p -quinones in acid media has been studied. A tentative mechanism of oxidation of ferrocene with p -qionone in acid media including two-step reduction of p-quinone to hydroquinone is proposed.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218100109