The growth of KNSH/KCSH bicrystals from aqueous solutions at a constant temperature difference

•A setup is proposed for growing KNSH/KCSH and KCSH/KNSH/KCSH bulk crystals from aqueous solutions.•It is shown that transmission intensity of crystals is related to defects in the heteroboundary.•KCSH/KNSH bicrystal shows transmission similar to that of mono-component crystals. The setup with a fee...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of crystal growth 2018-12, Vol.503, p.45-50
Hauptverfasser: Zhokhov, A.A., Masalov, V.M., Manomenova, V.L., Rudneva, E.B., Vasilyeva, N.A., Voloshin, A.E., Emelchenko, G.A.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•A setup is proposed for growing KNSH/KCSH and KCSH/KNSH/KCSH bulk crystals from aqueous solutions.•It is shown that transmission intensity of crystals is related to defects in the heteroboundary.•KCSH/KNSH bicrystal shows transmission similar to that of mono-component crystals. The setup with a feed zone for growing crystals from aqueous solutions at a constant temperature difference was implemented in this work. It combines feed and growth zones in one block. The capabilities of the setup developed were demonstrated by growing K2Ni(SO4)2·6H2O (KNSH)/K2Co(SO4)2·6H2O (KCSH) bicrystals and KCSH/KNSH/KCSH tricrystals. The influence of initial supercooling and substrate orientation on the inclusions formation at the KCSH/KNSH heteroboundary was studied by X-ray topography. The KCSH/KNSH bicrystal grown at 1 °C initial supercooling on the (1 1 0) KNSH substrate shows 77% transmission that is close to the transmission of mono-component Tutton salts and allows using bicrystals as optical filters of the solar-blind range.
ISSN:0022-0248
1873-5002
DOI:10.1016/j.jcrysgro.2018.09.033