Acetone: a solvent or a reagent depending on the addition order in SET-LRP

Acetone: a solvent or a reagent depending on the addition order in SET-LRP

Depending on the order of addition to the reaction mixture during biphasic SET-LRP performed in acetone/water mixtures, acetone can serve as a solvent or as a reagent brominated by CuBr 2 to provide the electrophilic bromoacetone initiator as well as aldol condensation products.

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Veröffentlicht in:Polymer chemistry 2018-12, Vol.9 (45), p.5411-5417
Hauptverfasser: Moreno, Adrian, Lejnieks, Jānis, Galià, Marina, Lligadas, Gerard, Percec, Virgil
Format: Artikel
Sprache:eng
Schlagworte:
Acetone
Aldehydes
Bromination
Condensates
Copper bromide
Polymer chemistry
Reagents
Solvents
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Zusammenfassung:Depending on the order of addition to the reaction mixture during biphasic SET-LRP performed in acetone/water mixtures, acetone can serve as a solvent or as a reagent brominated by CuBr 2 to provide the electrophilic bromoacetone initiator as well as aldol condensation products.
ISSN:1759-9954
1759-9962
DOI:10.1039/C8PY01331D