2H-Benzo[e]-1,2-oxaphosphorine Related Heterocycles as Precursors for the Synthesis of Unsymmetrical Bicyclic Phosphonates

2H-Benzo[e]-1,2-oxaphosphorine Related Heterocycles as Precursors for the Synthesis of Unsymmetrical Bicyclic Phosphonates

The reaction of 2-hydroxy-5,7,8-trimethyl-2-oxobenzo[ e ]-1,2-oxaphosphorine with thionyl chloride yielded the pyrophosphonate product, which was isolated and characterized for the first time. Subsequent treatment of it with phosphorus pentachloride led to the formation of new types of unsymmetrical...

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Veröffentlicht in:Russian journal of general chemistry 2018-09, Vol.88 (9), p.1941-1943
Hauptverfasser: Sadykova, Yu. M., Sadikova, L. M., Zalaltdinova, A. V., Sultanova, Z. N., Burilov, A. R., Pudovik, M. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chlorides
Dichloropropane
Letters to the Editor
Phosphonates
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Zusammenfassung:The reaction of 2-hydroxy-5,7,8-trimethyl-2-oxobenzo[ e ]-1,2-oxaphosphorine with thionyl chloride yielded the pyrophosphonate product, which was isolated and characterized for the first time. Subsequent treatment of it with phosphorus pentachloride led to the formation of new types of unsymmetrical cage phosphonates.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218090323