Effect of content of Al2O3 and MgO on crystallization of blast furnace slag during fiber formation

The simulation of blast furnace slag was prepared by pure chemical reagents. Test methods like DSC, XRD and SEM were used to study the effect of Al 2 O 3 and MgO content on crystallization of blast furnace slag during fiber formation. The results show that as Al 2 O 3 and MgO contents in the sample...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of Central South University 2018-10, Vol.25 (10), p.2373-2379
Hauptverfasser: Li, Zhi-hui, Zhang, Yong-jie, Zhang, Yu-zhu, Du, Pei-pei, Ren, Qian-qian
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The simulation of blast furnace slag was prepared by pure chemical reagents. Test methods like DSC, XRD and SEM were used to study the effect of Al 2 O 3 and MgO content on crystallization of blast furnace slag during fiber formation. The results show that as Al 2 O 3 and MgO contents in the sample changed, blast furnace slag was crystallized at the average temperature below 1232 K. When the ratio of Mg/Al in the samples is 0.6 calculated by Kissinger equation, crystallization activation energy is at the maximum value and the system is in the most stable condition. The sample crystallization phases are mainly calcium akermanite (2CaO·MgO·2SiO 2 ) and gehlenite (2CaO·Al 2 O 3 ·SiO 2 ). Secondary crystallization phases are anorthite (CaAl 2 Si 2 O 8 ), wollastonite minerals (WOLLA) and pyroxene minerals (cPyrA). Meanwhile, the principal crystallization phases of the samples are different types and have different contents, and the microstructures of the sample sections are different due to the difference between MgO/Al 2 O 3 ratio.
ISSN:2095-2899
2227-5223
DOI:10.1007/s11771-018-3921-6