Self‐Assembly of Perovskite Crystals Anchored Al2O3‐La2O3 Nanofibrous Membranes with Robust Flexibility and Luminescence

Inorganic luminescent materials as one of the important high‐performance materials are widely used for industry and scientific research, mainly owing to their outstanding luminescence properties. However, inorganic luminescent materials are typically brittle and inelastic, which greatly limit their use in practical applications, particularly in flexible optoelectronic devices. In this work, it is shown that “plum‐pudding” like CsPbBr3/Cs4PbBr6 perovskite crystals anchor onto Al2O3‐La2O3 (CCAL) nanofibrous membranes, which are synthesized via a facile electrospinning and subsequent supersaturated recrystallization process. The as‐synthesized CCAL membranes exhibit outstanding mechanical flexibility and luminescence properties. Meanwhile, the crystal structure and luminous performance of the CCAL membranes are regulated by different molar ratios of CsBr/PbBr2. The photoluminescence reaches a maximum value for the CCAL membranes produced with a CsBr/PbBr2 ratio of 1, and shows a narrow emission line‐width of 18 nm. Furthermore, the potential applications of the CCAL nanofibrous membranes in green light devices through a remote nanofibrous membranes packaging approach are demonstrated. A pure green emission is achieved with the Commission Internationale de L'Eclairage color coordinates of (0.28, 0.65). This facile strategy would open a new avenue to flexible inorganic luminescent materials for the lighting and backlight display industries. A fluorescent nanofibrous membrane with robust flexibility for the light‐emitting diodes of the (CsPbBr3/Cs4PbBr6)@Al2O3‐La2O3 membranes, which can be synthesized by anchoring “plum‐pudding” like perovskite crystals (CsPbBr3/Cs4PbBr6) onto Al2O3‐La2O3 nanofibers through a simple electrospinning and a subsequent supersaturated recrystallization process, is reported.