Carbotrifluoromethylation of Allylic Alcohols via 1,2‐Aryl Migration Promoted by Visible‐Light‐Induced Photoredox Catalysis
Visible‐light‐enabled photocatalytic carbotrifluoro‐methylations of allylic alcohols and sodium triflinate were explored through 1,2‐migration of an aryl group, affording an efficient method for synthesis of β‐trifluoromethyl‐α‐substituted carbonyl compounds under mild reaction conditions. This cata...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2018-11, Vol.360 (21), p.4084-4088 |
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| container_end_page | 4088 |
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| container_issue | 21 |
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| container_title | Advanced synthesis & catalysis |
| container_volume | 360 |
| creator | Cai, Shunyou Tian, Yu Zhang, Jinwang Liu, Zhiji Lu, Maojian Weng, Wen Huang, Mingqiang |
| description | Visible‐light‐enabled photocatalytic carbotrifluoro‐methylations of allylic alcohols and sodium triflinate were explored through 1,2‐migration of an aryl group, affording an efficient method for synthesis of β‐trifluoromethyl‐α‐substituted carbonyl compounds under mild reaction conditions. This catalyst system is well tolerant of various synthetically useful functional groups. |
| doi_str_mv | 10.1002/adsc.201800726 |
| format | Article |
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This catalyst system is well tolerant of various synthetically useful functional groups.</description><subject>1,2-aryl migration</subject><subject>Alcohol</subject><subject>Alcohols</subject><subject>Aromatic compounds</subject><subject>Carbonyl compounds</subject><subject>Carbonyls</subject><subject>carbotrifluoromethylation</subject><subject>Chemical synthesis</subject><subject>Functional groups</subject><subject>Langlois reagent</subject><subject>Migration</subject><subject>Photocatalysis</subject><subject>Photoredox catalysis</subject><subject>trifluoromethyl radical</subject><subject>visible light</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFUMlOwzAUtBBIlMKVcySutHhpFh-jsFUqohLLNfKWxpVbFzsBcoM_4Bv5ElwFlSOnedKbRTMAnCI4RhDiCya9GGOIMghTnOyBAUpQPJqghO7v7hgegiPvlxCiNEvTAfgsmOO2cboyrXV2pZq6M6zRdh3ZKsqN6YwWAYWtrfHRq2YROsffH1-560x0pxeuJ8-D1jZKRryLnrXX3KhAmulF3QScrmUrwnNe28Y6Je17VLCGmc5rfwwOKma8OvnFIXi6vnosbkez-5tpkc9GgmQkGVHGlSShGU25SGQVJyzGseRChlaEQ05jAWGWJDEnUMgKUxxnhNAM8ixlk4oMwVnvu3H2pVW-KZe2desQWWIUjCkmIWgIxj1LOOu9U1W5cXrFXFciWG5nLrczl7uZg4D2gjdtVPcPu8wvH4o_7Q-_fYXs</recordid><startdate>20181105</startdate><enddate>20181105</enddate><creator>Cai, Shunyou</creator><creator>Tian, Yu</creator><creator>Zhang, Jinwang</creator><creator>Liu, Zhiji</creator><creator>Lu, Maojian</creator><creator>Weng, Wen</creator><creator>Huang, Mingqiang</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20181105</creationdate><title>Carbotrifluoromethylation of Allylic Alcohols via 1,2‐Aryl Migration Promoted by Visible‐Light‐Induced Photoredox Catalysis</title><author>Cai, Shunyou ; Tian, Yu ; Zhang, Jinwang ; Liu, Zhiji ; Lu, Maojian ; Weng, Wen ; Huang, Mingqiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3836-9abed307297bc6df56a525dbcd4153b0b95c008665b30cdf2925833980b87a4f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>1,2-aryl migration</topic><topic>Alcohol</topic><topic>Alcohols</topic><topic>Aromatic compounds</topic><topic>Carbonyl compounds</topic><topic>Carbonyls</topic><topic>carbotrifluoromethylation</topic><topic>Chemical synthesis</topic><topic>Functional groups</topic><topic>Langlois reagent</topic><topic>Migration</topic><topic>Photocatalysis</topic><topic>Photoredox catalysis</topic><topic>trifluoromethyl radical</topic><topic>visible light</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cai, Shunyou</creatorcontrib><creatorcontrib>Tian, Yu</creatorcontrib><creatorcontrib>Zhang, Jinwang</creatorcontrib><creatorcontrib>Liu, Zhiji</creatorcontrib><creatorcontrib>Lu, Maojian</creatorcontrib><creatorcontrib>Weng, Wen</creatorcontrib><creatorcontrib>Huang, Mingqiang</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cai, Shunyou</au><au>Tian, Yu</au><au>Zhang, Jinwang</au><au>Liu, Zhiji</au><au>Lu, Maojian</au><au>Weng, Wen</au><au>Huang, Mingqiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbotrifluoromethylation of Allylic Alcohols via 1,2‐Aryl Migration Promoted by Visible‐Light‐Induced Photoredox Catalysis</atitle><jtitle>Advanced synthesis & catalysis</jtitle><date>2018-11-05</date><risdate>2018</risdate><volume>360</volume><issue>21</issue><spage>4084</spage><epage>4088</epage><pages>4084-4088</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>Visible‐light‐enabled photocatalytic carbotrifluoro‐methylations of allylic alcohols and sodium triflinate were explored through 1,2‐migration of an aryl group, affording an efficient method for synthesis of β‐trifluoromethyl‐α‐substituted carbonyl compounds under mild reaction conditions. 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| source | Wiley Online Library |
| subjects | 1,2-aryl migration Alcohol Alcohols Aromatic compounds Carbonyl compounds Carbonyls carbotrifluoromethylation Chemical synthesis Functional groups Langlois reagent Migration Photocatalysis Photoredox catalysis trifluoromethyl radical visible light |
| title | Carbotrifluoromethylation of Allylic Alcohols via 1,2‐Aryl Migration Promoted by Visible‐Light‐Induced Photoredox Catalysis |
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