Synthesis and characterization of novel poly(ethylene furanoate-co-adipate) random copolyesters with enhanced biodegradability

In this study, copolymers based on poly(ethylene furanoate) (PEF) and poly(ethylene adipate) (PEAd) were synthesized by melt polycondensation using 2,5-dimethyl furan dicarboxylate (DMFD), adipic acid (AA) and ethylene glycol (EG) in different proportions. The success of the reaction, crystallograph...

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Veröffentlicht in:	Polymer degradation and stability 2018-10, Vol.156, p.32-42
Hauptverfasser:	Papadopoulos, Lazaros, Magaziotis, Andreas, Nerantzaki, Maria, Terzopoulou, Zoi, Papageorgiou, George Z., Bikiaris, Dimitrios N.
Format:	Artikel
Sprache:	eng
Schlagworte:	2,5-Furandicarboxylic acid Adipic acid Biobased polymers Biodegradability Biodegradation Chemical synthesis Cocrystallization Copolymers Crystallography Differential scanning calorimetry Enzymatic hydrolysis Ethylene glycol Fourier transforms Magnetic properties Melt polycondensation Molecular weight NMR Nuclear magnetic resonance poly(ethylene furanoate-co-adipate) copolymers Polyesters Polyethylene Thermal stability Thermodynamic properties Thermogravimetric analysis X ray spectra X-ray diffraction
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