Synthesis and characterization of novel poly(ethylene furanoate-co-adipate) random copolyesters with enhanced biodegradability

In this study, copolymers based on poly(ethylene furanoate) (PEF) and poly(ethylene adipate) (PEAd) were synthesized by melt polycondensation using 2,5-dimethyl furan dicarboxylate (DMFD), adipic acid (AA) and ethylene glycol (EG) in different proportions. The success of the reaction, crystallographic characteristics, molecular weight and thermal properties were determined with Nuclear Magnetic Resonance Spectroscopy (1H NMR), Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). The results confirm the successful synthesis of random copolymers, with high thermal stability, which exceeds 300 °C. Also, isodimorphic cocrystallization was concluded from both XRD patterns and DSC thermograms. The enzymatic hydrolysis rate of the copolyesters depended on comonomer ratio. Copolymers with 95 and 90 mol% of ethylene adipate (EAd) were completely degraded after 30 days. •Fully biobased poly (ethylene furanoate-co-ethylene Adipate) (PEFAd) copolymers were synthesized for first time.•All copolymers are random.•All copolymers have high thermal stability, which is ranged between this of neat polyesters.•Copolymers with EAd content 95 and 90 mol% have the highest enzymatic hydrolysis.