Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes

Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes

In this work, Zn 2+ and Cu 2+ ions are doped into a Mn 2+ based frail MOF (STU-2) to form heterometallic MOFs. These metal doped MOFs show a good stability and heterogeneous catalytic activity for the cyanosilylation reactions of aromatic aldehydes. The catalysts can be reused at least for three cyc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry frontiers 2018-11, Vol.5 (11), p.2772-2776
Hauptverfasser: Du, Jia-Jia, Zhang, Xiang, Zhou, Xiao-Ping, Li, Dan
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Catalysis
Catalysts
Catalytic activity
Copper
Inorganic chemistry
Metal-organic frameworks
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this work, Zn 2+ and Cu 2+ ions are doped into a Mn 2+ based frail MOF (STU-2) to form heterometallic MOFs. These metal doped MOFs show a good stability and heterogeneous catalytic activity for the cyanosilylation reactions of aromatic aldehydes. The catalysts can be reused at least for three cycles.
ISSN:2052-1553
2052-1545
2052-1553
DOI:10.1039/C8QI00811F